Chromium-based bcc-superalloys strengthened by iron supplements

نویسندگان

چکیده

Chromium alloys are being considered for next-generation concentrated solar power applications operating > 800 °C. Cr offers advantages in melting point, cost, and oxidation resistance. However, improvements mechanical performance needed. Here, Cr-based body-centred-cubic (bcc) of the type Cr(Fe)-NiAl investigated, leading to ‘bcc-superalloys’ comprising a bcc-Cr(Fe) matrix (β) strengthened by ordered-bcc NiAl intermetallic precipitates (β’), with iron additions tailor precipitate volume fraction properties at high temperatures. Computational design using CALculation PHAse Diagram (CALPHAD) predicts that Fe increases solubility Ni Al, increasing fraction, which is validated experimentally. Nano-scale, highly-coherent B2-NiAl lattice misfit ∼ 0.1% formed Cr(Fe) matrix. The A2-B2 show remarkably low coarsening rate (∼102 nm3/h 1000 °C), outperforming ferritic-superalloys, cobalt- nickel-based superalloys. Low interfacial energies 40/20 mJ/m2 1000/1200 °C determined based on kinetics. rates principally attributed Al compressive yield strength ∼320 MPa Fe-modified alloy exhibits resistance age softening, related as well relatively stable Orowan strengthening function radius. Microstructure tailoring new route improve balance “Cr-superalloys”, accelerating their development class high-temperature materials.

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ژورنال

عنوان ژورنال: Acta Materialia

سال: 2023

ISSN: ['1873-2453', '1359-6454']

DOI: https://doi.org/10.1016/j.actamat.2023.119183